Authorities say that some sort of "chemical device" went off just before noon.
Three students and a teacher have been hospitalized due to exposure, while nine other patients required treatment.
Parents were able to pick up their children from the school's gym, which was taken off the evacuation list after it was deemed safe by emergency crews.
No further information has yet been released about what occurred at the school.
The Douglas County Sheriff's Office, Littleton Fire Department, and South Metro Fire Department are investigating the incident.
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